INORGANIC MATERIALS RESEARCH GROUP PUBLICATION LIST ON  MINERALOGICAL TOPICS

1982

Barron, P.F., Wilson, M.A., Campbell, A.S. and Frost, R.L. (1982) Detection of imogolite in soils using solid state silicon-29 NMR. Nature (London), 299, 616-18.

1983

Barron, P.F., Frost, R.L. and Skjemstad, J.O. (1983) Silicon-29 spin-lattice relaxation in aluminosilicates. J. Chem. Soc., Chem. Commun., 581-3.

Barron, P.F., Frost, R.L., Skjemstad, J.O. and Koppi, A.J. (1983) Detection of two silicon environments in kaolins by solid-state silicon-29 NMR. Nature (London), 302, 49-50.

Frost, R.L. and Barron, P.F. (1983) Solid-state silicon-29 and aluminium-27 nuclear magnetic resoance investigation of the dehydroxylation of pyrophyllite. J. Physical Chemistry, 88, 6206-6209.

Skjemstad, J.O., Frost, R.L. and Barron, P.F. (1983) Structural units in humic acids from south-eastern Queensland soils as determined by carbon-13 NMR spectroscopy. Aust. J. Soil Res., 21, 539-47.

1985

Barron, P.F. and Frost, R.L. (1985) Solid state silicon-29 NMR examination of the 2:1 ribbon magnesium silicates, sepiolite and palygorskite. Am. Mineral., 70, 758-66.

Barron, P.F., Slade, P. and Frost, R.L. (1985) Ordering of aluminum in tetrahedral sites in mixed-layer 2:1 phyllosilicates by solid-state high-resolution NMR. J. Phys. Chem., 89, 3880-5.

Barron, P.F., Slade, P. and Frost, R.L. (1985) Solid-state silicon-29 spin-lattice relaxation in several 2:1 phyllosilicate minerals. J. Phys. Chem., 89, 3305-10.

1989

Frost, R.L., Parker, R.W. and Hanna, J.V. (1989) Detection of the pesticide compound 1080 (sodium monofluoroacetate) using fluorine-19 nuclear magnetic resonance spectroscopy. Analyst (London), 114, 1245-8.

1990

Kloprogge, J.T., Eerden, A.M.J. v.d., Jansen, J.B.H. and Geus, J.W. (1990) Hydrothermal synthesis of Na-beidellite. Geologie en Mijnbouw, 69, 351-357.

Kloprogge, J.T., Jansen, J.B.H. and Geus, J.W. (1990) Characterization of synthetic Na-beidellite. Clays and Clay Minerals, 38, 409-414.

1992

Kloprogge, J.T., Jansen, J.B.H., Schuiling, R.D. and Geus, J.W. (1992) The interlayer collapse during dehydration of synthetic Na_0.7-beidellite: A ²³Na solid state Magic-Angle spinning NMR study. Clays and Clay Minerals, 40, 561-566.

1993

Frost, R.L., Fredericks, P.M. and Bartlett, J.R. (1993) Fourier transform Raman spectroscopy of kandite clays. Spectrochim. Acta, Part A, 49A, 667-74.

Kloprogge, J.T., Breukelaar, J., Jansen, J.B.H. and Geus, J.W. (1993) Development of ammonium-saponites from gels with variable ammonium concentration and water content at low temperatures. Clays and Clay Minerals, 41, 103-110.

Kloprogge, J.T., Eerden, A.M.J. v.d., Jansen, J.B.H., Geus, J.W. and Schuiling, R.D. (1993) Synthesis and paragenesis of Na-beidellite as a function of temperature , water pressure, and sodium activity. Clays and Clay Minerals, 41, 423-430.

1994

Frost, R.L. and Vassallo, A.J. (1994) Dehydroxylation of the kandite and imogolite clay minerals. 14th Australian Clay Minerals Conference, Kalgoorie, Australia.

Kloprogge, J.T. (1994) Synthesis of aluminum expanded clay a new type of form-selective sieve in heterogeneous catalyst. Tijdschr. Klei, Glas Keram., 15, 218-21.

Kloprogge, J.T., Booij, E., Jansen, J.B.H. and Geus, J.W. (1994) The effect of thermal treatment on the properties of hydroxy-Al and hydroxy-Ga pillared montmorillonite and beidellite. Clay Minerals, 29, 153-167.

Kloprogge, J.T., Booij, E., Jansen, J.B.H. and Geus, J.W. (1994) Synthesis of Al-pillared beidellite and its catalytic activity in the hydroconversion of n-heptane. Catalysis Letters, 29, 293-297.

Kloprogge, J.T., Breukelaar, J., Geus, J.W. and Jansen, J.B.H. (1994) Characterization of Mg-saponites synthesised from gels containing amounts of Na⁺, K⁺, Rb⁺, Ca²⁺, Ba²⁺, or Ce⁴⁺ equivalent to the CEC of the saponite. Clays and Clay Minerals, 42, 18-22.

Kloprogge, J.T., Breukelaar, J., Wilson, A.E., Geus, J.W. and Jansen, J.B.H. (1994) Solid-state nuclear magnetic resonance spectrscopy on synthetic ammonium/aluminum-saponites. Clays and Clay Minerals, 42, 416-420.

Visser, D., Kloprogge, J.T. and Maijer, C. (1994) An infrared spectroscopic (IR) and light element (Li, Be, Na) study of cordierites from the Bamble Sector, South Norway. Lithos, 32, 95-107.

1995

Frost, R.L. (1995) Fourier transform Raman spectroscopy of Kaolinite, dickite and halloysite. Clay and Clay Minerals, 43, 191-195.

Frost, R.L., Collins, B.M., Finnie, K. and Vassallo, A.J. (1995) Infrared emission spectroscopy of clay minerals and their thermal transformations. In G.J. Churchman, R.W. Fitzpatrick, and R.A. Eggleton, Eds. Clays Controlling the Environment, Proc. Int. Clay Conf., 10th, p. 219-24. CSIRO Publishing, Melbourne, Adelaide, Australia.

Kloprogge, J.T. and Vogels, R. (1995) Hydrothermal synthesis of ammonium-beidellite. Clays and Clay Minerals, 43, 135-137.

Parker, R.W. and Frost, R.L. (1995) Analysis of organic chemicals on bentonitic clays using diffuse reflectance Fourier transform infrared spectroscopy. Clays Controlling Environ., Proc. Int. Clay Conf., 10th, 300-3.

Vogels, R.J.M.J., Kloprogge, J.T., Buining, P.A., Seykens, D., Jansen, J.B.H. and Geus, J.W. (1995) The tridecameric aluminum comlpex as an appropriate precursor for fibrous boehmite: a  ²⁷Al NMR study on the partial hydrolysis of aluminum sec-butoxide. J. Non-Crystalline Solids, 191, 38-44.

1996

Booij, E., Kloprogge, J.T. and Veen, J.A.R.v. (1996) Large pore REE /Al-pillared bentonites: Preparation, structural aspects and catalytic properties. Applied Clay Science, 11, 155-162.

Booij, E., Kloprogge, J.T. and Veen, J.A.R.v. (1996) Preparation, structural characteristics and catalytic properties of large-pore rare earth element (Ce/La)/Al-pillared smectites. Clays and Clay Minerals, 44, 774-782.

Frost, R.L. (1996) The application of Raman microscopy to the study of minerals. Chem. Aust., 63, 446-448.

Frost, R.L., Fredericks, P.M. and Shurvell, H.F. (1996) Raman microscopy of some kaolinite clay minerals. Canadian Journal of Applied Spectroscopy, 41, 11-14.

Frost, R.L. and Rintoul, L. (1996) Lattice vibrations of montmorillonite: an FT Raman and X-ray diffraction study. Applied Clay Science, 11, 171-183.

Frost, R.L. and Rintoul, L. (1996) FT Raman spectroscopy of montmorillonites. Int. Ceram. Monogr., 2, 325-331.

Frost, R.L. and Vassallo, A.M. (1996) The dehydroxylation of the kaolinite clay minerals using infrared emission spectroscopy. Clays and Clay Minerals, 44, 635.

Kloprogge, J.T., Vogels, R.J.M.J. and van der Eerden, A.M.J. (1996) Hydrothermal synthesis of pyrophyllite from Si-Al gels and salt solutions. Neues Jahrb. Mineral., Monatsh., 135-44.

Parker, R.W. and Frost, R.L. (1996) The application of Drift spectroscopt to the multicomponent analysis or organic chemicals adsorbed on montmorillonite. Clays and Clay Minerals, 44, 32-39.

1997

Frost, R.L. (1997) The structure of the kaolinite clay minerals - a FT Raman study. Clay Minerals, 32, 73-85.

Frost, R.L. and Gaast, S.J. v.d. (1997) Kaolinite hydroxyls - A Raman microscopy study. Clays and Clay Minerals, 45, 68-72.

Frost, R.L. and Kloprogge, J.T. (1997) De toepassing van Raman spectroscopie in de bestudering van kleimineralen. Klei Glas en Keramiek, 19, 22-25.

Frost, R.L. and Kloprogge, J.T. (1997) Infrarood emissie spectroscopie, een nieuwe techniek om o.a. de dehydroxylatie van kleimineralen in situ te bestuderen. Klei Glas en Keramiek, 19, 11-15.

Frost, R.L. and Kristof, J. (1997) Intercalation of Halloysite - A Raman spectroscopic study. Clays and Clay Minerals, 45, 68-72.

Frost, R.L. and Parker, R.W. (1997) Drift spectroscopy for determination of organic acids on montmorillonite. Mikrochim. Acta, Suppl., 14, 691-692.

Frost, R.L. and Paroz, G.N. (1997) The dehydroxylation of urea intercalated kaolinite: an infrared emission spectroscopic study. Clays Our Future, Proc. Int. Clay Conf., 11th, 403-408.

Frost, R.L., Paroz, G.N. and Van Der Gaast, S.J. (1997) Hydrogen bonding in kaolinite. Clays Our Future, Proc. Int. Clay Conf., 11th, 393-396.

Frost, R.L., Rintoul, L. and Eggleton, R.A. (1997) Structural aspects of hisingerite: a vibrational spectroscopic study. Clays Our Future, Proc. Int. Clay Conf., 11th, 409-412.

Frost, R.L. and Shurvell, H.F. (1997) Raman microprobe spectroscopy of Halloysite. Clays and Clay Minerals, 45, 68-72.

Frost, R.L., Tran, T.H. and Kristof, J. (1997) The structure of an intercalated ordered kaolinite - a Raman microscopy study. Clay Minerals, 32, 587-596.

Frost, R.L., Tran, T.H. and Kristof, J. (1997) FT-Raman spectroscopy of the lattice region of kaolinite and its intercalates. Vibrational Spectroscopy, 13, 175-186.

Frost, R.L., Tran, T.H. and Kristof, J. (1997) Intercalation of an ordered kaolinite - a Raman microscopy study. Clay Minerals, 32, 587-596.

Frost, R.L., Tran, T.H. and Li, T. (1997) Fourier Transform Raman spectroscopy of Kaolinite. Mikrochimica Acta, 14, 747-749.

Frost, R.L., Tran, T.H.T. and Kristof, J. (1997) The structure of intercalated kaolinite: a Raman and infrared spectroscopic study. Clays Our Future, Proc. Int. Clay Conf., 11th, 397-401.

Frost, R.L. and Van Der Gaast, S.J. (1997) Kaolinite hydroxyls - a Raman microscopy study. Clay Miner., 32, 471-484.

Frost, R.L. and Vassallo, A.M. (1997) Fourier-transform infrared emission spectroscopy of kaolinite dehydroxylation. Mikrochim. Acta, Suppl., 14, 789-791.

Kristof, J., Frost, R.L., Felinger, A. and Mink, J. (1997) FTIR spectroscopic study of intercalated kaolinite. J. Mol. Struct., 410-411, 119-122.

Kristof, J., Toth, M., Gabor, M., Szabo, P. and Frost, R.L. (1997) Study of the structure and thermal behavior of intercalated kaolinites. J. Therm. Anal., 49, 1441-1448.

Parker, R.W. and Frost, R.L. (1997) The use of diffuse reflectance infrared spectroscopy to study organic acid-montmorillonite adsorption. Clays Our Future, Proc. Int. Clay Conf., 11th, 357-360.

Van der Gaast, S.J., Kuhnel, R.A., Vasterink, J. and Frost, R.L. (1997) A new model for the structure of water in the interlayer of Ca-Wyoming montmorillonite. Clays Our Future, Proc. Int. Clay Conf., 11th, 421-427.

Vogels, R.J.M.J., Breukelaar, J., Kloprogge, J.T., Jansen, J.B.H. and Geus, J.W. (1997) Hydrothermal crystallization of ammonium-saponite at 200^oC and autogenous water pressure. Clays and Clay Minerals, 45, 1-7.

1998

Frost, R.L. (1998) Hydroxyl deformation in kaolins. Clays and Clay Minerals, 46, 280-289.

Frost, R.L., Cash, G.A. and Kloprogge, J.T. (1998) 'Rocky Mountain Leather', sepiolite and attapulgite-an infrared emission spectroscopic study. Vibrational Spectroscopy, 16, 173-184.

Frost, R.L., Forsling, W., Holmgren, A., Kloprogge, J.T. and Kristof, J. (1998) Raman Spectroscopy at temperatures between 298 and 423K and at 77K of kaolinites intercalated with formamide. J. Raman Spectroscopy, 29, 1065-1069.

Frost, R.L. and Johansson, U. (1998) Combination bands in the infrared spectroscopy of kaolins - a DRIFT spectroscopy study. Clays and Clay Minerals, 46, 466-477.

Frost, R.L. and Kloprogge, J.T. (1998) IR emission spectroscopy. A new method for in situ studies of the dehydroxylation of clay minerals. Tijdschr. Klei, Glas Keram., 19, 11-15.

Frost, R.L. and Kloprogge, J.T. (1998) Application of Raman spectroscopy in the investigation of clay minerals. Tijdschr. Klei, Glas Keram., 19, 22-25.

Frost, R.L., Kloprogge, J.T., Kristof, J. and Horvath, E. (1998) Vibrational spectroscopic study of dimethylsulphoxide intercalated kaolinites. 3rd Australian Conference on Vibrational Spectroscopy, p. 170-171, University of Melbourne, Australia.

Frost, R.L., Kloprogge, J.T., Kristof, J. and Horvath, E. (1998) Raman spectroscopy of hydrazine intercalated kaolinites. 3rd Australian Conference on Vibrational Spectroscopy, p. 180-181, University of Melbourne, Australia.

Frost, R.L., Kloprogge, J.T., Tran, T.H.T. and Kristof, J. (1998) The effect of pressure on the intercalation of an ordered kaolinite. American Mineralogist, 83, 1182-1187.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (1998) Molecular structure of dimethylsulphoxide intercalated kaolinites. 16th Australian Clay Minerals Society Conference, CIDC, QUT.

Frost, R.L., Kristof, J., Paroz, G.N. and Kloprogge, J.T. (1998) Molecular structure of dimethyl sulfoxide intercalated kaolinites. J. Physical Chemistry B, 102, 8519-8532.

Frost, R.L., Kristof, J., Paroz, G.N. and Kloprogge, J.T. (1998) Modification of the kaolinite hydroxyl surfaces through intercalation with potassium acetate under pressure. J. Colloid and Interface Science, 208, 478-486.

Frost, R.L., Kristof, J., Paroz, G.N. and Kloprogge, J.T. (1998) The role of water in the intercalation of kaolinite with hydrazine. J. Colloid and Interface Science, 208, 216-225.

Frost, R.L., Kristof, J., Paroz, G.N. and Kloprogge, J.T. (1998) Raman spectroscopy of intercalated Kaolinites. 16th International Conference on Raman Spectroscopy, p. 686-687, Cape Town, South Africa.

Frost, R.L., Kristof, J., Paroz, G.N., Tran, T.H. and Kloprogge, J.T. (1998) The role of water in the intercalation of kaolinite with potassium acetate. J. Colloid and Interface Science, 204, 227-236.

Frost, R.L., Kristof, J. and Tran, T.H. (1998) Kinetics of deintercalation of potassium acetate from kaolinite - a Raman spectroscopic study. Clay Minerals, 33, 605-617.

Frost, R.L., Paroz, G.N., Tran, T.H. and Kristof, J. (1998) FT-Raman and FTIR spectroscopy of intercalated kaolinites. AIP Conf. Proc., 430, 681-684.

Frost, R.L., Tran, T.H., Rintoul, L. and Kristof, J. (1998) Raman microscopy of dickite, kaolinite and their intercalates. The Analysts, 123, 611-616.

Fry, R.L., Kloprogge, J.T. and Frost, R.L. (1998) The application of clays for the coating of fertilizer particles. 16th Australian Clay Minerals Society Conference, CIDC, QUT.

Fry, R.L., Kloprogge, J.T. and Frost, R.L. (1998) FTIR study of synthetic and natural beidellites. 16th Australian Clay Minerals Society Conference, CIDC, QUT.

Johansson, U., Frost, R.L., Forsling, W. and Kloprogge, J.T. (1998) Raman spectroscopy of the kaolinite hydroxyls at 77K. 3rd Australian Conference on Vibrational Spectroscopy, p. 168-169, University of Melbourne, Australia.

Johansson, U., Frost, R.L., Forsling, W. and Kloprogge, J.T. (1998) Raman spectroscopy of the kaolinite hydroxyls at 77 K. Appl. Spectrosc., 52, 1277-1282.

Johansson, U., Holmgren, A., Forsling, W. and Frost, R. (1998) Isotopic exchange of kaolinite hydroxyl protons: a diffuse reflectance infrared Fourier transform spectroscopy study. Analyst (Cambridge, U. K.), 123, 641-645.

Kloprogge, J.T. (1998) Synthesis of smectites and porous pillared clay catalysts: Review. J. Porous Materials, 5, 5-42.

Kloprogge, J.T., Frost, R.L. and Fry, R. (1998) FTIR study of synthetic and natural beidellites. 3rd Australian Conference on Vibrational Spectroscopy, p. 180-181, University of Melbourne, Australia.

Kloprogge, J.T., Frost, R.L. and Kristof, J. (1998) Application of infrared emission spectroscopy for the study of the dehydroxylation of synthetic paragonite. Can. J. Anal. Sci. Spectros., 44, 33-36.

Kloprogge, J.T., Frost, R.L. and Lack, D. (1998) An infrared emission spectroscopy study of synthetic and natural pyrophyllite. 3rd Australian Conference on Vibrational Spectroscopy, p. 176-177, University of Melbourne, Australia.

Kloprogge, J.T., Frost, R.L. and Parker, R.W. (1998) The effect of synthesis temperature on the FT-Raman spectra of saponites. 16th International Conference on Raman Spectroscopy, p. 698-699, Cape Town, South Africa.

Kloprogge, J.T., Komarneni, S., Yanagisawa, K., Frost, R.L. and Fry, R. (1998) Infrared study of some synthetic and natural beidellites. J. Mater. Sci. Lett., 17, 1853-1855.

Kloprogge, J.T., Vogels, R.J.M.J., Jansen, J.B.H. and Geus, J.W. (1998) Synthetic clay minerals as shape selective heterogeneous catalysts. 16th Australian Clay Minerals Society Conference, CIDC, QUT.

Kristof, J., Frost, R.L., Horvath, E., Kocsis, L. and Inczedy, J. (1998) Thermoanalytical investigations on intercalated kaolinites. J. Therm. Anal. Calorim., 53, 467-475.

Kristof, J., Frost, R.L., Kloprogge, J.T., Gabor, M. and Toth, M. (1998) Thermoanalytical investigation on intercalated kaolinites. 7th European symposium on thermal analysis and calorimetry, p. 319, Balatonfured, Hungary.

Leishman, N., Kloprogge, J.T. and Frost, R.L. (1998) FT-Raman spectroscopy of Mg/Zn/Al-hydrotalcites. 3rd Australian Conference on Vibrational Spectroscopy, p. 80-81, University of Melbourne, Australia.

Leishman, N., Kloprogge, J.T., Fry, R. and Frost, R.L. (1998) FT-Raman and FTIR spectroscopy of synthetic Mg/Zn/Al-hydrotalcites. 16th Australia Clay Minerals Society Conference, p. June 29-July 1, CIDC, QUT.

Parker, R.W. and Frost, R.L. (1998) Monitoring the sorption of propanoic acid by montmorillonite using diffuse reflectance Fourier transform infrared spectroscopy. AIP Conf. Proc., 430, 671-673.

Paroz, G.N. and Frost, R.L. (1998) Chemometric investigation of diorder in kaolinite. The Analyst, 123, 2813-2817.

Paroz, G.N., Frost, R.L. and Cash, G.A. (1998) Dehydroxylation of intercalated kaolinite, an infrared emission spectroscopic study. AIP Conf. Proc., 430, 678-680.

Rintoul, L., Panayiotou, H., Kokot, S., George, G., Cash, G., Frost, R., Bui, T. and Fredericks, P. (1998) Fourier transform infrared spectrometry: a versatile technique for real world samples. Analyst (Cambridge, U. K.), 123, 571-577.

Szetu, J., Kloprogge, J.T. and Frost, R.L. (1998) Infrared emission spectroscopy of alumina phases and gels. 3rd Australian Conference on Vibrational Spectroscopy, p. 166-167, University of Melbourne, Australia.

1999

Frost, R.L., Kloprogge, J.T., Russell, S.C. and Szetu, J. (1999) Dehydroxylation of aluminum (oxo)hydroxides using infrared emission spectroscopy, Part II: Boehmite. Applied Spectroscopy, 53.

Frost, R.L. and Kloprogge, J.T. (1999) Infrared emission spectroscopic study of brucite. Spectrochimica Acta Part A, 55, 2195-2205.

Frost, R.L. and Kloprogge, J.T. (1999) Raman spectroscopy of the low-frequency region of kaolinite at 298 and 77K. Applied Spectroscopy, 53, 1610-1616.

Frost, R.L., Kloprogge, J.T., Kristof, J. and Horvath, E. (1999) Deintercalation of hydrazine-intercalated low-defect kaolinite. Clays and Clay Minerals, 47, 732-741.

Frost, R.L., Kloprogge, J.T., Russell, S.C. and Szetu, J. (1999) Dehydroxylation and the vibrational spectroscopy of aluminum (oxo)hydroxides using infrared emission spectroscopy. Part III: diaspore. Appl. Spectrosc., 53, 829-835.

Frost, R.L., Kloprogge, J.T., Russell, S.C. and Szetu, J. (1999) Dehydroxylation of aluminum (oxo)hydroxides using infrared emission spectroscopy. Part II: Boehmite. Appl. Spectrosc., 53, 572-582.

Frost, R.L., Kloprogge, J.T., Russell, S.C. and Szetu, J.L. (1999) Vibrational spectroscopy and dehydroxylation of aluminum (Oxo)hydroxides: gibbsite. Appl. Spectrosc., 53, 423-434.

Frost, R.L., Kloprogge, J.T. and Schmidt, J. (1999) Non-destructive identification of minerals by Raman microscopy. J. Vibrational Spectrscopy, 3, 2.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (1999) Deintercalation of dimethylsulphoxide intercalated kaolinites - a DTA/TGA and Raman spectroscopic study. Thermochimica Acta, 327, 155-166.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (1999) Modification of kaolinite surfaces with cesium acetate at 25, 120, and 220^oC. Langmuir, 15, 8787-8794.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (1999) Modification of the kaolinite hydroxyl surfaces through the application of pressure and temperature. Part III. J. Colloid and Interface Science, 214, 380-388.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (1999) Modification of the kaolinite hydroxyl surfaces through intercalation with potassium acetate, II. J. Colloid and Interface Science, 214, 109-117.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (1999) Modification of Kaolinite Surfaces with Cesium Acetate at 25, 120, and 220°C. Langmuir, 15, 8787-8794.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (1999) Molecular Structure of Dimethyl Sulfoxide in DMSO-Intercalated Kaolinites at 298 and 77 K. J. Phys. Chem. A, 103, 9654-9660.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (1999) Deintercalation of dimethyl sulfoxide intercalated kaolinites - a DTA/TGA and Raman spectroscopic study. Thermochim. Acta, 327, 155-166.

Frost, R.L., Kristof, J., Horvath, E. and Klorogge, J.T. (1999) Molecular structure of dimethyl sulfoxide in DMSO-intercalated kaolinites at 298 and 77K. J. Physical Chemistry A, 103, 9654-9660.

Frost, R.L., Kristof, J., Paroz, G.N. and Kloprogge, J.T. (1999) Intercalation of kaolinite with acetamide. Phys. Chem. Minerals, 26, 257-263.

Frost, R.L., Lack, D.A., Paroz, G.N. and Tran, T.H.T. (1999) New techniques for studying the intercalation of kaolinites from Georgia with formamide. Clays and Clay Minerals, 47, 297-303.

Johansson, U., Holmgren, A., Forsling, W. and Frost, R.L. (1999) Adsorption of silane coupling agents onto kaolinite surfaces. Clay Minerals, 34, 241-248.

Kloprogge, J.T. and Frost, R.L. (1999) Fourier Transform Infrared and Raman spectroscopic study of the local structure of Mg-, Ni-, and Co-hydrotalcites. J. Solid State Chemistry, 146, 506-515.

Kloprogge, J.T. and Frost, R.L. (1999) Raman microprobe spectroscopy of hydrated Halloysite from a neogene cryptokarst from Southern Belgium. J. Raman Spectroscopy, 30, 1078-1085.

Kloprogge, J.T. and Frost, R.L. (1999) Infrared emission spectroscopic study of the dehydroxylation of synthetic Mg/Al and Mg/Al/Zn hydrotalcites. Physical Chemisty, Chemical Physics, 1, 1641-1647.

Kloprogge, J.T. and Frost, R.L. (1999) Raman -en infrarood spectroscopische studie van de intercalatie van kaoliniet met organische moleculen. Klei Glas en Keramiek, 20, 20-24.

Kloprogge, J.T. and Frost, R.L. (1999) An infrared emission spectroscopy study of synthetic and natural pyrophyllite. N. Jb. Miner. Mh, 62-74.

Kloprogge, J.T. and Frost, R.L. (1999) Infrared emission spectroscopic study of some natural and synthetic paragonites. Applied Spectroscopy, 53, 1071-1077.

Kloprogge, J.T. and Frost, R.L. (1999) Raman microscopy study of cafarsite. Applied Spectroscopy, 53, 874-879.

Kloprogge, J.T. and Frost, R.L. (1999) Raman Microscopic study of some borate minerals: Ulexite, Kernite, and Inderite. Applied Spectroscopy, 53, 356-363.

Kloprogge, J.T. and Frost, R.L. (1999) Infrared emission spectroscopy of Al-pillared beidellite. Applied Clay Sciencce, 15, 431-445.

Kloprogge, J.T. and Frost, R.L. (1999) Infrared emission spectroscopic study of the thermal transformation of Mg-, Ni-, and Co-hydrotalcite catalysts. Applied Catalysis A: General, 184, 61-71.

Kloprogge, J.T. and Frost, R.L. (1999) Raman and infrared spectroscopic study of the intercalation of kaolinite with organic molecules. Tijdschr. Klei, Glas Keram., 20, 26-30.

Kloprogge, J.T. and Frost, R.L. (1999) A Raman microscopic study of tungstate and molybdate minerals: scheelite, wolframite and wulfenite. Neues Jahrb. Mineral., Monatsh., 193-211.

Kloprogge, J.T. and Frost, R.L. (1999) Nondestructive identification of minerals by Raman microscopy. Tijdschr. Klei, Glas Keram., 20, 22-26.

Kloprogge, J.T. and Frost, R.L. (1999) An infrared emission spectroscopic study of synthetic and natural pyrophyllite. Neues Jahrb. Mineral., Monatsh., 62-74.

Kloprogge, J.T. and Frost, R.L. (1999) Niet-destructieve identificatie van mineralen met behulp van Raman microscopie. Klei Glas en Keramiek, 20, 22-26.

Kloprogge, J.T. and Frost, R.L. (1999) Raman and Infrared microscopy study of zunyite, a natural Al-13 silicate. Spectrochimica Acta Part A, 55, 1505-1513.

Kloprogge, J.T. and Frost, R.L. (1999) Raman microsporbe spectroscopy of hydrated Halloysite from a neogene cryptokarst from Southern Belgium. J. Raman Spectroscopy, 30, 1078-1085.

Kloprogge, J.T. and Frost, R.L. (1999) Raman en infrarood spectroscopische studie van de intercalatie van kaoliniet met organische moleculen, Deel 1: Groep A en B moleculen. Klei Glas en Keramiek, 20, 20--24.

Kloprogge, J.T. and Frost, R.L. (1999) Raman en infrarood spectroscopische studie van de intercalatie van kaoliniet met organische moleculen, Deel 2: Groep C moleculen. Klei Glas en Keramiek, 20, 26-30.

Kloprogge, J.T. and Frost, R.L. (1999) Infrared emission spectroscopic study of the dehydroxylation of synthetic Mg/Al and Mg/Zn/Al-hydrotalcites. Physical Chemistry, Chemical Physics, 1, 1641-1647.

Kloprogge, J.T., Frost, R.L. and Fry, R. (1999) Infrared emission study of the thermal transformation mechanism of Al₁₃-pillared clay. The Analyst, 124, 381-384.

Kloprogge, J.T., Frost, R.L. and Hickey, L.A. (1999) Infrared absorption and emission study of synthetic mica-montmorillonite in comparison to rectorite, beidellite and paragonite. J. Materials Science Letters, 18, 1921-1923.

Kloprogge, J.T., Frost, R.L. and Kristof, J. (1999) Complex expansion of kaolinite with hydrazine ; some preliminary observations. N. Jb. Miner. Mh, 49-61.

Kloprogge, J.T., Frost, R.L. and Kristof, J. (1999) Application of infrared emission spectroscopy for the study of the dehydroxylation of synthetic paragonite. Can. J. Anal. Sci. Spectrosc., 44, 33-36.

Kloprogge, J.T., Frost, R.L. and Rintoul, L. (1999) Single crystal Raman microscopic study of the asbestos mineral in chrysotile. Physical Chemistry, Chemical Physics, 1, 2559-2564.

Kloprogge, J.T., Fry, R. and Frost, R.L. (1999) An infrared emission spectroscopic study of the thermal transformation mechanisms in Al13-pillared clay catalysts with and without tetrahedral substitutions. J. Catalysis, 184, 157-171.

Kloprogge, J.T., Hickey, L. and Frost, R.L. (1999) Infrared study of some synthetic saponites: Effect of NH₄/Al and H₂O/(Si+Al) ratios during the crystallization. J. Materials Science Letters, 18, 1401-1403.

Kloprogge, J.T., Komarneni, S. and Amonette, J.E. (1999) Synthesis of smectite clay minerals: A critical review. Clays and Clay Minerals, 47, 529-554.

Kloprogge, J.T., Komarneni, S., Yanagisawa, K., Fry, R. and Frost, R.L. (1999) Infrared emission spectroscopic study of the dehydroxylation via surface silanol groups of synthetic and natural beidellite. J. Colloid and Interface Science, 212, 562-569.

Kloprogge, T., Frost, R. and Lack, D. (1999) Non-Destructive identification of minerals by Raman microscopy. Chemistry in Australia, p. 40-44, Brisbane.

Kristof, J., Frost, R.L., Kloprogge, J.T., Horvath, E. and Gabor, M. (1999) Thermal behaviour of kaolinite intercalated with formamide, dimethyl sulphoxide and hydrazine. J. of Thermal Analysis and Calorimetry, 56, 885-891.

2000

Frost, R.L. and Kloprogge, J.T. (2000) Raman Spectroscopy of Nacrite single crystals at 298 and 77K. Spectrochimica Acta Part A, 56, 931-939.

Frost, R.L. and Kloprogge, J.T. (2000) Raman spectroscopy of the acetates of sodium, potassium and magnesium at liquid nitrogen temperature. J. Mol. Struct., 526, 131-141.

Frost, R.L. and Kloprogge, J.T. (2000) Raman spectroscopy of kaolinite hydroxyls between 25.degree.C and 500.degree.C. J. Raman Spectrosc., 31, 415-420.

Frost, R.L. and Kloprogge, J.T. (2000) Raman spectroscopy of nontronites. Appl. Spectrosc., 54, 402-405.

Frost, R.L. and Kloprogge, J.T. (2000) Raman microscopy of kaolinite phases expanded through intercalation with potassium acetate. Institute of Physics, Conference Series, 165 Symposium 1, 93-94.

Frost, R.L. and Kloprogge, J.T. (2000) Raman spectroscopy of kaolinite hydroxyls between 25°C and 500°C. Journal of Raman Spectroscopy, 31, 415-420.

Frost, R.L. and Kloprogge, J.T. (2000) Vibrational spectroscopy of ferruginous smectite and nontronite. Spectrochim. Acta, Part A, 56, 2177-2189.

Frost, R.L., Kloprogge, J.T., Williams, P.A. and Leverett, P. (2000) Raman microscopy of some natural pseudo-alums: halotrichite, apjohnite and wupatkiite, at 298 and 77 K. Journal of Raman Spectroscopy, 31, 1083-108.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (2000) Vibrational spectroscopy of formamide-intercalated kaolinites. Spectrochimica Acta Part A, 56, 1191-1204.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (2000) Kaolinite hydroxyls in dimethylsulphoxide intercalated kaolinites at 77K - a Raman spectroscopic study. Clay Minerals, 35, 443-454.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (2000) Effect of water on the formamide-intercalation of kaolinite. Spectrochim. Acta, Part A, 56A, 1711-1729.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (2000) Rehydration and phase changes of potassium acetate-intercalated halloysite at 298 K. J. Colloid Interface Sci., 226, 318-327.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (2000) Kaolinite hydroxyls in dimethylsulphoxide-intercalated kaolinites at 77 K - a Raman spectroscopic study. Clay Miner., 35, 443-454.

Frost, R.L., Kristof, J. and Kloprogge, J.T. (2000) New phases of kaolinite expanded with potassium acetate - A XRD and Raman study. In C.S.F. Gomes, Ed. First Latin-American Clay Conference, 17-22 september 2000, 1, p. 292-305. Associacao Portueguesa de argilas (APA), Funchal, Madeira, Portugal.

Frost, R.L., Kristof, J., Kloprogge, J.T. and Horvath, E. (2000) Rehydration of potassium acetate-intercalated kaolinite at 298 K. Langmuir, 16, 5403-5409.

Frost, R.L., Kristof, J., Mako, E. and Kloprogge, J.T. (2000) Modification of the hydroxyl surface in potassium-acetate-intercalated kaolinite between 25 and 300°C. Langmuir, 16, 7421-7428.

Frost, R.L., Kristof, J., Mako, E. and Kloprogge, J.T. (2000) Modification of the hydroxyl surface of potassium acetate intercalated halloysite between 25 and 300°C. American Mineralogist, 85, 1735-1743.

Frost, R.L., Kristof, J., Rintoul, L. and Kloprogge, J.T. (2000) Raman spectroscopy of urea and urea-intercalated kaolinites at 77 K. Spectrochim. Acta, Part A, 56A, 1681-1691.

Frost, R.L., Ruan, H. and Kloprogge, J.T. (2000) Application of infrared emission spectroscopy to the study of  natural and synthetic materials. Internet J. Vibrational Spectroscopy, 4, 1-12.

Frost, R.L., Ruan, H., Kloprogge, J.T. and Gates, W.P. (2000) Dehydration and dehydroxylation of notronites and ferruginous smectite. Thermochimica Acta, 346, 63-72.

Hickey, L., Kloprogge, J.T. and Frost, R.L. (2000) The effects of various hydrothermal treatments on magnesium-aluminium hydrotalcites. Journal of Materials Science, 35, 4347-4355.

Kloprogge, J.T. and Frost, R.L. (2000) The effect of synthesis temperature on the FT-Raman and FT-IR spectra of samponites. Vibrational Spectroscopy, 23, 119-127.

Kloprogge, J.T. and Frost, R.L. (2000) Raman microscopic study at 300 and 77K of some pegmatite minerals from the Iveland-Evje area, Aust-Agder, Southern Norway. Spectrochimica Acta Part A, 56, 501-513.

Kloprogge, J.T. and Frost, R.L. (2000) Raman microscopy at 77K of natural gypsum CaSO₄.2H₂O. J. Materials Science Letters, 19, 229-231.

Kloprogge, J.T. and Frost, R.L. (2000) Thermal decomposition of Ferrian chamosite: an infrared emission spectroscopic study. Contrib. Mineral. Petrol, 138, 59-67.

Kloprogge, J.T. and Frost, R.L. (2000) Raman microscopy study of tyrolite: a multi-anion arsenate mineral. Appl. Spectrosc., 54, 517-521.

Kloprogge, J.T. and Frost, R.L. (2000) Introduction to syntheses and uses of hydrotalcites. Tijdschr. Klei, Glas Keram., 21, 7-11, 27.

Kloprogge, J.T. and Frost, R.L. (2000) Study of the thermal behaviour of rectorite by in-situ infrared emission spectroscopy. Neues Jahrb. Mineral., Monatsh., 145-157.

Kloprogge, J.T. and Frost, R.L. (2000) The effect of synthesis temperature on the FT-Raman and FT-IR spectra of saponites. Vib. Spectrosc., 23, 119-127.

Kloprogge, J.T. and Frost, R.L. (2000) Raman microscopy at 77K of natural gypsum CaSO4.cntdot.2H2O. J. Mater. Sci. Lett., 19, 229-231.

Kloprogge, J.T. and Frost, R.L. (2000) Raman spectroscopic study at 300 and 77 K of some pegmatite minerals from the Iveland-Evje area, Aust-Agder, southern Norway. Spectrochim. Acta, Part A, 56A, 501-513.

Kloprogge, J.T. and Frost, R.L. (2000) Raman microscopy as non-destructive method for the analysis of minerals. Institute of Physics, Conference Series, 165 Symposium 1, 89-90.

Kloprogge, J.T. and Frost, R.L. (2000) Infrared emission spectroscopic study of the dehydroxylation of 10 Å halloysite from a Neogene cryptokarst of South Belgium. Geologica Belgica, 2, 213-220.

Kloprogge, J.T. and Frost, R.L. (2000) Reply on "Comments on 'Infrared emission spectroscopic study of the thermal transformation of Mg-, Ni- and Co-hydrotalcite catalysts' by J. Perez-Ramirez, G. Mul, F. Kapteijn and J.A. Moulijn. Applied Catalysis A: General, 204, 269-270.

Kloprogge, J.T., Frost, R.L. and Hickey, L. (2000) Infrared emission spectroscopic study of the dehydroxylation of some hectorites. Thermochim. Acta, 345, 145-156.

Kloprogge, J.T., Hammond, M. and Frost, R.L. (2000) Low temperature synthesis and characterisation of pecoraite, a nickel containing phyllosilicate. Neues Jahrb. Mineral., Monatsh., 193-206.

Kloprogge, J.T., Hickey, L. and Frost, R.L. (2000) The effect of increasing layer charge on the infrared absorption spectra of synthetic beidellites. J. Mater. Sci. Lett., 19, 1131-1134.

Kloprogge, J.T., Hickey, L. and Frost, R.L. (2000) Synthesis and spectroscopic characterisation of deuterated hydrotalcite. New Journal of Chemistry, submitted.

Kloprogge, J.T., Ruan, H. and Frost, R.L. (2000) Near-infrared spectroscopic study of synthetic and natural pyrophyllite. Neues Jahrb. Mineral., Monatsh., 337-347.

Kloprogge, J.T., Wharton, D. and Frost, R.L. (2000) Raman and infrared spectroscopy of interlayer CO₃^2-, NO₃^-, SO₄^2- and ClO₄^- in hydrotalcites. ICORS 2000, p. 96, Beijing, China.

Kristof, J., Horvath, E., Frost, R.L. and Kloprogge, J.T. (2000) Thermoanalytical investigation of formamide intercalated kaolinites under quasi-isothermal conditions. Journal of Thermal Analysis and Calorimetry, 63, 279-289.

Szetu, J.L., Frost, R.L., Kloprogge, J.T., Russell, S.C. and Martens, W. (2000) Dehydration and dehydroxylation of alumina gels prepared from tri-sec-butoxyaluminium modified with short chain aliphatic acids. Thermochimica Acta, 362, 37-48.

2001

Crane, M.J.,  Leverett, P., Shaddick, L.R., Williams, P.A.,  Kloprogge, J.T. and  Frost, R. L. (2001), The PbCrO₄-PbSO₄ system and its mineralogical significance. Neues Jahrbuch für Mineralogie, Monatshefte, (11), 505-519.

Ding, Z., Kloprogge,J.T.,   Frost,R.L.,  Lu, G.Q.  and Zhu, H.Y.  (2001) Smectites and porous pillared clay catalysts. Part 2: A review of the catalytic and molecular sieve applications. Journal of Porous Materials, 8(4), 273-293.

Frost, R.L. and Kloprogge, J.T. (2001) Towards a single crystal Raman spectrum of kaolinite at 77 K. Spectrochimica Acta, 57, 163-175

Frost, R.L. and Kloprogge, J.T. (2001) Raman microscopy of kalinite and tschermigite and lonecreekite at 298 and 77K. Neues Jahrbuch für Mineralogie, Monatshefte, 27-40.

Frost, R.L., Kristof, J., Schmidt, J.M. and Kloprogge, J.T. (2001) Raman spectroscopy of potassium acetate-intercalated kaolinites at liquid nitrogen temperature. Spectrochimica Acta, 57, 603-609.

Frost, R.L., Ding, Z. and Kloprogge, J.T. (2001) The application of near-infrared spectroscopy to the study of brucite and hydrotalcite structures. Canadian Journal of Analytical Science and Spectroscopy, 45(4), 96-102.

Frost, R.L., Kristof, J., Kloprogge, J.T. and Horvath, E. (2001) Modification of the hydroxyl surface in cesium acetate intercalated kaolinite. Langmuir, 17(13), 4067-4073.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (2001) Separation of adsorbed formamide and intercalated formamide using controlled rate thermal analysis methodology, Langmuir, 17(11), 3216-3222.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (2001) The modification of hydroxyl surfaces of formamide-intercalated kaolinites synthesized using controlled rate thermal analysis. Journal of Colloid and Interface Science, 239(1), 126-133.

Frost, R.L., Locos, O.B., Kristof, J. and Kloprogge, J.T. (2001) Infrared spectroscopic study of potassium and cesium acetate-intercalated kaolinites. Vibrational Spectroscopy, 26(1), 33-42.

Frost, R.L., Kristof, J. and Kloprogge, J.T. (2001) Raman spectroscopy of potassium acetate-intercalated kaolinites over the temperature range 25 to 300°C. Journal of Raman Spectroscopy, 32, 271-277.

Frost, R.L., Makó, É., Kristof, J., Horvath, E. and Kloprogge, J.T. (2001) Modification of kaolinite surfaces by thermomechanical treatment. Langmuir, 17(16),  4731-4738.

Frost, R.L.,  Makó, É., Kristof, J., Horvath, E. and Kloprogge, J.T.  (2001) Mechanochemical treatment of kaolinite. Journal of Colloid and Interface Science, 239, 458-466.

Frost, R.L.,  Fredericks, P.M., Kloprogge, J.T. and Hope, G.A. (2001) Raman spectroscopy of kaolinites using different excitation wavelengths, Journal of Raman Spectroscopy, 32(8), 657-663.

Frost, R.L., Kristof, J., Horvath, E. and Kloprogge, J.T. (2001) Raman microscopy of hydroxyl surfaces of formamide-intercalated kaolinites treated by controlled rate thermal analysis technology. Journal of Raman Spectroscopy, 32(10), 873-880.

Frost, R.L., Locos, O.B., Ruan, H. and Kloprogge, J.T. (2001) Near-infrared and mid-infrared spectroscopic study of sepiolites and palygorskites. Vibrational Spectroscopy, 27(1), 1-13.

Frost, R.L., Williams, P.A., Kloprogge, J.T. and Leverett, P. (2001) Raman spectroscopy of descloizite and mottramite at 298 and 77 K. Journal of Raman Spectroscopy, 32(11), 906-911.

Kloprogge, J.T., Ruan, H. and Frost, R.L. (2001) Near-infrared spectroscopic study of basic aluminum sulfate and nitrate. Journal of Materials Science, 36(3), 603-607.

Kloprogge, J.T., Hickey, L. and Frost, R.L. (2001) Heating stage Raman and infrared emission spectroscopic study of the dehydroxylation of synthetic Mg-hydrotalcite. Appl. Clay Sci, 18(1-2) 37-49.

Kloprogge, J.T, Visser, D., Case, M.H. and Frost, R.L. (2001) Raman microscopic study of holmquistite, a Li-bearing orthorhombic amphibole. Neues Jahrbuch für Mineralogie, Monatshefte, 1-17.

Kloprogge, J.T., van Veen, J.A.R.,  Booij, E.  and Frost, R.L.  (2001) Comments on “Enhanced thermal stability of Al-pillared smectites modified with Ce and La” by J.L. Valverde, P. Canizares, M.R. Sun Kou and C.B. Molina. Clays and Clay Minerals, 49(2), 183-185.

Kloprogge, J.T., Hammond, M., Hickey, L. and Frost, R.L. (2001) A new low temperature synthesis route of fraipontite (Zn,Al)₃(Si,Al)₂O₅(OH)₄. Materials Research Bulletin, 36, 1091-1098.

Kloprogge, J.T., Ruan, H. and Frost, R.L. (2001) FT-IR and Raman microscopic study at 293 K and 77 K of celestine, SrSO₄, from the middle triassic limestone (Muschelkalk) in Winterswijk, The Netherlands. Geologie en Mijnbouw/Netherlands Journal of Geosciences, 80(2), 41-47.

 Kloprogge, J. T., Visser, D., Ruan, H. and  Frost, R. L. (2001) Infrared and Raman spectroscopy of holmquistite, Li₂(Mg,Fe²⁺)₃(Al,Fe³⁺)₂(Si,Al)₈O₂₂(OH)₂. Journal of Materials Science Letters, 20(16), 1497-1499.

Kloprogge, J.T. and Frost, R.L. (2001) Infrared emission spectroscopic study of the dehydroxylation of some natural and synthetic saponites. Neues Jahrbuch für Mineralogie, Monatshefte, (10), 446-463.

Kloprogge, J.T., Case, M.H. and Frost, R.L. (2001) Raman microscopic study of the Li-amphibole holmquistite, from the Martin Marietta Quarry, Bessemer City, NC., U.S.A., Mineralogical Magazine, 65(6), 775-785.

Kristóf, E. Horváth, R. L. Frost and J. T. Kloprogge (2000) Thermoanalytical investigation of formamide intercalated kaolinites under quasi-isothermal conditions Journal of Thermal Analysis and calorimetry, 63(1), 279-289.

Martens. W.N., Frost, R.L. and Kloprogge, J.T. (2001) The ageing of alumina hydrolysates synthesized from secbutoxyaluminium(III). Journal of Materials Chemistry, 11(6), 1681-1686.

Martens. W.N., Frost, R.L. and Kloprogge, J.T. (2001) Thermal transformation of alumina hydrolysates and gels synthesized from secbutoxyaluminium(iii) with short chain aliphatic acids dissolved in butyl ether. Thermochimica Acta, 374(1), 31-43.

Mendelovici, E., Frost, R.L. and Kloprogge, J.T. (2001) Modification of chrysotile surface by organosilanes: An IR-Photoacoustic spectroscopy study. Journal of Colloid and Interface Science, 238(2), 273-278.

Ruan, H.D., Frost, R.L. and Kloprogge, J.T. (2001) The application of near-infrared spectroscopy to the study of alumina phases. Applied Spectroscopy, 55(2), 190-196.

Ruan, H.D., Frost, R.L. and Kloprogge, J.T. (2001) Comparison of Raman spectra in characterizing gibbsite, bayerite, diaspore and boehmite. Journal of Raman spectroscopy, 32(9), 745-750.

Ruan, H.D., Frost, R.L. and Kloprogge, J.T. (2001) The behavior of the hydroxyl unit of synthetic goethite and its dehydroxylated product hematite. Spectrochimica Acta, 57(13), 2575-2586.

 2002

Ruan, H.D., Frost, R.L., Kloprogge, J.T. and Duong, L. (2002) Far-infrared spectroscopy of alumina phases. Spectrochimica Acta Part A, 58(2), 265-272. 

 Kloprogge, J.T., Evans, R., Hickey, L. and Frost, R.L. (2002) Characterisation and Al-pillaring of smectites from Miles, Queensland (Australia). Applied Clay Science 20(4-5), 157-163 (Special issue on clay research in Australia and New Zealand). 

Frost, R.L., van der Gaast, S.J., Zbik, M., Kloprogge, J.T. and Paroz, G.N. (2002) Birdwood kaolinite (South Australia) – an XRD, SEM and Raman spectroscopic study. Applied Clay Science 20(4-5), 177-187 (Special issue on clay research in Australia and New Zealand). 

Frost, R.L., Edwards, H.G.H., Duong, L., Kloprogge, J.T. and Martens, W.N. (2002) Raman spectroscopic and SEM study of cinnabar from Herod's palace and its likely origin. The Analyst, 127(2), 293-296. 

Martens, W.N., Frost, R.L., Kristof, J and Kloprogge, J.T. (2002) Raman spectroscopy of hydrazine-intercalated kaolinite at 77, 298, 323, 343 and 358 K. Journal of Raman Spectroscopy, 33(1), 31-36.

 Frost, R.L., Kristof, J., Kloprogge, J.T. and Horvath, E. (2002) Deintercalation of hydrazine intercalated kaolinite in dry and moist air. Journal of Colloids and Interface Science, 246(1), 164-174.  

Ruan, H.D., Frost, R.L., Kloprogge, J.T. and Duong, L. (2002) Infrared spectroscopy of goethite dehydroxylation II. Effect of Al substitution on the behaviour of hydroxyl units.  Spectrochimica Acta Part A, 58(3), 479-491.

 Martens, W.N., Kloprogge, J.T., Frost, R.L. and Bartlett, J.R. (2002) A crystallite packing model for pseudoboehmite formed during the hydrolysis of trisecbutoxyaluminium to explain the peptizability. Journal of Colloid and Interface Science, 247(1), 132-137. 

Ruan, H.D., Frost, R.L., Kloprogge, J.T. and Duong, L. (2002) Infrared spectroscopy of goethite dehydroxylation III. FT-IR microscopy of in situ study of the thermal transformation of goethite to hematite. Spectrochimica Acta Part A, 58, 967-981.

 Crane, M., Frost, R.L., Williams, P.A. and Kloprogge, J.T. (2002) Raman spectroscopy of the molybdate minerals: chillagite (tunsteinian wulfenite-(I-4)), wolframite and wulfenite, Journal of Raman Spectroscopy, 33(1), 62-66.

 Martens, W.N., Frost, R.L., Kristof, J. and Kloprogge, J.T. (2002) Raman Spectroscopy of dimethylsulphoxide and deuterated dimethylsulphoxide at 298 and 77K. J. Raman Spectroscopy, 33(2), 84-91.

 Kloprogge, J.T., Schuiling, R.D., Ding, Z., Hickey, L., Ruan, H., Wharton, D. and Frost, R.L. (2002) Vibrational spectroscopic study of syngenite formed during the treatment of liquid manure with sulphuric acid. Vibrational Spectroscopy, 28, 209-221.

Kloprogge, J.T., Wharton, D., Hickey, L. and Frost, R.L. (2002) Infrared and Raman study of interlayer anions CO₃^2-, NO₃^-, SO₄^2- and ClO₄^- in Mg/Al-hydrotalcite. American Mineralogist, 87(3) 623-629. 

De Oliveira, L.F.C., Edwards, H.G.M., Frost, R.L., Kloprogge, J.T. and Middleton, P.S. (2002) Caput mortuum: spectroscopic and structural studies of an ancient pigment. The Analyst, 127, 536-541. 

Kloprogge, J.T., Ruan, H.D. and Frost, R.L. (2002) Thermal decomposition of bauxite minerals: infrared emission spectroscopy of gibbsite, boehmite and diaspore. Journal of Materials Science, 37(6), 1121-1129. 

Frost, R.L., Martens, W. N., Rintoul, L., Mahmutagic, E. and Kloprogge, J.T. (2002) Raman spectroscopic study of azurite and malachite at 298 and 77K.  J. Raman Spectroscopy, 33(4), 252-259. 

Frost, R.L., Williams, P.A., Martens, W.N., Kloprogge, J.T. and Leverett, P. (2002) Raman spectroscopy of the basic copper phosphate minerals: cornetite, libethenite, pseudomalachite, reichenbachite and ludjibaite. Journal of Raman Spectroscopy, 33(4), 260-263. 

Frost, R.L, Kloprogge, J.T. and Ding, Z. (2002) Near-infrared spectroscopic study of nontronites and ferruginous smectite. Spectrochimica Acta Part A, 58, 1657-1668.

Frost, R.L., Kloprogge, J.T. and Ding, Z. (2002) The Garfield and Uley nontronites - An infrared spectroscopic comparison. Spectrochimica Acta Part A, 58, 1881-1894.

J. Theo Kloprogge, Leisel Hickey and Ray L. Frost (2002) Synthesis and spectroscopic characterisation of deuterated hydrotalcite. Journal of Materials Science Letters, 21(8), 603-605.

Kloprogge, J.T., Hammond, M., Hickey, L. and Frost, R.L. (2002) Low temperature synthesis of Cobalt clays. Journal of Materials Science Letters, 21(12), 931-933.

 Frost, R.L., Ding, Z., Kloprogge, J.T. and Martens, W.N. (2002) Thermal stability of azurite and malachite in relation to the formation of mediaeval glass and glazes. Thermochimica Acta, 390(1-2), 133-144.

Ding, Z., Frost, R.L. and Kloprogge, J.T. (2002) Thermal activation of copper carbonate. Journal of Materials Letters, 21(13), 981-983. 

Frost, R.L., Kristof, J., Horvath, E., Martens, W.N. and Kloprogge, J.T. (2002) Complexity of intercalation of hydrazine into kaolinite – a controlled rate thermal analysis and DRIFT spectroscopic study. Journal of Colloid and Interface Science, 251(2), 350-359.

Kloprogge, J.T. and Frost, R.L. (2002) Infrared Emission Spectroscopy Of Clay And Related Minerals. In “Encyclopedia of Surface and Colloid Science”, ed. A. Hubbard, Marcel Dekker Inc., New York, 2490-2513.

 Frost, R.L. and Kloprogge, J.T. (2002) Raman and infrared spectroscopic study of the modification of kaolinite surfaces by organic molecules. In “Encyclopedia of Surface and Colloid Science”, ed. A. Hubbard, Marcel Dekker Inc., New York, 4438-4452. 

Johnson, T.E., Martens, W.N., Frost, R.L., Ding, Z. and Kloprogge, J.T. (2002) Structured water in hydrotalcites of formula Mg_xZn_6-xAl₂(OH)₁₆(CO₃).4H₂O: a Raman microscopic study. Journal of Raman Spectroscopy, 33(8), 604-609. 

Frost, R.L., Martens, W.N., Duong, L. and Kloprogge, J.T. (2002) Evidence for molecular assembly in hydrotalcites. Journal of Materials Science Letters, 219(16), 1237-1239. 

Kristóf, J., Kloprogge, J.T., Frost, R.L., Horváth, E. and Makó, É. (2002) Detection of four different OH-groups in kaolinite with Controlled-Rate Thermal Analysis. Journal of Thermal Analysis, 69, 77-83. 

Frost, R.L., Williams, P.A., Martens, W.N. and Kloprogge, J.T. (2002) Raman spectroscopy of the polyanionic copper(II) minerals buttgenbachite and connelite: implications for studies of ancient copper objects and bronzes. Journal of Raman Spectroscopy, 33, 752-757. 

Frost, R.L., Martens, W.N., Kloprogge, J.T. and Williams, P.A. (2002) Vibrational spectroscopy of basic manganese and ferric phosphate minerals: Strunzite, ferrostrunzite and ferristrunzite. Neues Jahrbuch für Mineralogie, Monatshefte, (11), 481-496. 

Frost, R.L., Martens, W.N., Kloprogge, J.T. and Williams, P.A. (2002) Raman spectroscopy of the basic copper chloride minerals atacamite and paratacamite; implications for the study of copper, brass and bronze objects of archaeological significance. Journal of Raman Spectroscopy, 33(10), 801-806. 

R.L. Frost, É. Makó, J. Kristóf and J.T. Kloprogge (2002) Modification of kaolinite surfaces through mechanochemically treatment - A mid-IR and Near-IR spectroscopic study. Spectrochimica Acta, 58, 2849-2859.

Frost, R.L., Williams, P.A., Martens, W.N., Johnson, T.E., Leverett, P. and Kloprogge, J.T. (2002) Vibrational spectroscopy of the basic copper phosphate minerals: pseudomalachite, ludjibaite and reichenbachite. Spectrochimica Acta, 58, 2861-2868. 

 Frost, R.L., Martens, W.N., Kloprogge, J.T. and Crane, M.A. (2002) Raman spectroscopic study of cinnabar (HgS), realgar (As₄S₄), and orpiment (As₂S₃) at 298 and 77K, Neues Jahrbuch für Mineralogie, Monatshefte, (10), 469-480.

Frost, R.L., Ding, Z., Martens, W.N., Johnson, T.E. and Kloprogge, J.T. (2002) Molecular assembly in synthesized hydrotalcites of formula Cu_xZn_6-xAl₂(OH)₁₆(CO₃).4H₂O – a vibrational spectroscopic study. Spectrochimica Acta, 59, 321-328. 

Frost, R.L., Martens, W.N., Ding, Z., Kloprogge, J.T. and Johnson, T.E. (2002) The role of water in synthesized hydrotalcites of formula Mg_xZn_6-xCr₂(OH)₁₆(CO₃).4H₂O and Ni_xCo_6-xCr₂(OH)₁₆(CO₃).4H₂O – an infrared spectroscopic study. Spectrochimica Acta, 59, 291-302. 

Kristof, Janos; Frost, Ray L.; Martens, Wayde N.; Horvath, Erzsebet. (2002) Separation of Adsorbed and Intercalated Hydrazine in Hydrazine-Hydrate Intercalated Kaolinite by Controlled-Rate Thermal Analysis. Langmuir 18(4), 1244-1249.

Edwards, Howell G. M.; de Oliveira, Luiz F. C.; Middleton, Paul; Frost, Ray L. (2002) Romano-British wall-painting fragments: a spectroscopic analysis. Analyst, 127(2), 277-281. 

Martens, Wayde N.; Frost, Ray L.; Kristof, Janos; Horvath, Erzsebet. (2002) Modification of Kaolinite Surfaces through Intercalation with Deuterated Dimethylsulfoxide. Journal of Physical Chemistry B, 106(16), 4162-4171. 

Wilson, Gregory J.; Will, Geoffrey D.; Frost, Ray L.; Montgomery, Simon A.  Efficient microwave hydrothermal preparation of nanocrystalline anatase TiO2 colloids. Journal of Materials Chemistry (2002), 12(6), 1787-1791. 

Ding, Z.; Frost, R. L. (2002) Controlled rate thermal analysis of nontronite. Thermochimica Acta, 389(1-2), 185-193.

Frost, Ray L.; Martens, Wayde N.; Williams, Peter A. (2002) Raman spectroscopy of the phase-related basic copper arsenate minerals olivenite, cornwallite, cornubite and clinoclase. Journal of Raman Spectroscopy, 33(6), 475-484. 

Frost, Ray L.; Kristof, Janos; Mako, Eva; MartensWayde N. (2002) Modification of the Hydroxyl Surface of Kaolinite through Mechanochemical Treatment Followed by Intercalation with Potassium Acetate. Langmuir, 18(17), 6491-6498.

Ding, Z.; Martens, W.; Frost, R. L.. (2002) Thermal activation of copper nitrate. Journal of Materials Science Letters, 21(18), 1415-1417.  

Frost. R.L., Martens, W.N., Williams, P.A. and Kloprogge, J.T. (2002) Raman and Infrared spectroscopic study of the vivianite phosphates vivianite, baricite and bobierrite. Mineralogical Magazine, 66(6), 1063-1073.